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Chemistry HL IA Calculating activation energy of the decomposition of Hydrogen Peroxide with different catalysts


IBstudent8888

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My chemistry IA investigates the different activation energy of the decomposition of H202 with Lead oxide and manganese oxide. My teacher told me to plot 1/Temp against Ln x 1/ Average Time taken but not how to actually calculate Ea.

How do I get the activation energy if I have the time it takes for the percentage of oxygen to rise by 15% at 5 different temperatures and have it plotted 1/Temp against Ln x 1/ Average Time taken using the Arrhenius equation.

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From the Arrhenius equation, k = A exp (-Ea/(RT)), taking ln of both sides

ln k = ln A - Ea/(RT) = -(Ea/R) T + ln A, which is the equation of a line with slope -Ea/R and vertical intercept of ln A. So if you know the slope you can find the activation energy

k is the rate constant such that the "rate of change of [H2O2]" = Δ[H2O2]/Δt = k [H2O2] (first order rate law). By unit analysis, k has dimension of inverse time.

Hope that helps. There should also be videos online of teachers walking through the data processing. 

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